Thermal stability of the cu-ceo2 interface on silica and alumina, and its relation with activity in the oxidation reaction of co and the decomposition of n2o

Pablo Alvarez, Gonzalo Aguila, Sichem Guerrero, Paulo Araya

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2 Scopus citations

Abstract

The effect of the support on the formation of the Cu-CeO2 interface and its thermal stability after calcination at 500, 700 and 900 °C is studied. The supports used are SiO2, because of its inert character, and Al2O3, because it can interact with the Cu and Ce species on the surface. The catalysts were characterized by BET, XRD, UV-vis DRS, and TPR with H2. The catalytic activity in the CO oxidation reactions with O2 at low temperature and the decomposition of N2O were selected to visualize the effect of temperature on the concentration of Cu-CeO2 interfacial sites. The results show that at a calcination temperature of 500 °C the formation of the Cu-CeO2 interface is favored over the SiO2 support. However, the stability of the Cu-CeO2 interface on SiO2 is much lower than on Al2O3, causing a substantial decrease of the interfacial sites calcining at 700 °C, and segregation of the Cu and Ce species on the surface of the silica, with complete loss of the catalytic activity in both reactions when calcining at 900 °C. In contrast, on alumina the Cu-CeO2 interface is more stable and presents a significant catalytic activity in both reactions, even when calcining at 900 °C. The characterization results show that the sintering process of Cu species and CeO2 particles is less on the alumina support due to the greater interaction of the Cu and Ce with this support.

Original languageEnglish
Pages (from-to)4102-4108
Number of pages7
JournalJournal of the Chilean Chemical Society
Volume63
Issue number3
DOIs
StatePublished - 2018

Bibliographical note

Funding Information:
The authors acknowledge gratefully the financial support of this work

Publisher Copyright:
© 2018 Sociedad Chilena de Quimica.all rights reserved.

Keywords

  • Alumina
  • Ce
  • Co oxidation
  • Cu
  • No decomposition.
  • Silica

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