About the endothermal transitions of galactomannans: A multi-analytical DSC, LF- 1 H NMR and DMA study

Verónica M. Busch; Patricio R. Santagapita; Paulo Díaz-Calderón; Javier I. Enrione; M. Pilar Buera

doi:10.1016/j.carbpol.2019.01.092

About the endothermal transitions of galactomannans: A multi-analytical DSC, LF- ¹ H NMR and DMA study

Verónica M. Busch, Patricio R. Santagapita, Paulo Díaz-Calderón, Javier I. Enrione, M. Pilar Buera

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In the present work two galactomannans, vinal gum and guar gum, were evaluated by DSC, DMA and LF- 1 H NMR in order to compare them, establishing their potential operational application range and promoting the use of the non-conventional VG in foods or other products. Three endothermal transitions appeared when heating the samples in the DSC: one at temperatures −90 to −10 °C (LTT), other around 50 °C (MTT) and a third one between 50 and 100 °C (HTT). Both LTT and HTT showed water content dependence and low ΔC p values, which difficulted the assignment of a glass transition. MTT appeared as an enthalpic relaxation independent on frequency or on water content. This transition was related to changes in mechanical properties and with the stabilization of proton mobility.

Original language	American English
Pages (from-to)	31-38
Number of pages	8
Journal	Carbohydrate Polymers
Volume	211
DOIs	https://doi.org/10.1016/j.carbpol.2019.01.092
State	Published - 1 May 2019

Keywords

Biopolymer
Differential scanning calorimetry
Dynamic mechanical analysis
Enthalpic relaxation
Galactomannan (PubChem CID: 439336)
Guar gum
Guar gum (PubChem CID: 44134661)
Low field 1H NMR

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title = "About the endothermal transitions of galactomannans: A multi-analytical DSC, LF- 1 H NMR and DMA study",

abstract = "In the present work two galactomannans, vinal gum and guar gum, were evaluated by DSC, DMA and LF- 1 H NMR in order to compare them, establishing their potential operational application range and promoting the use of the non-conventional VG in foods or other products. Three endothermal transitions appeared when heating the samples in the DSC: one at temperatures −90 to −10 °C (LTT), other around 50 °C (MTT) and a third one between 50 and 100 °C (HTT). Both LTT and HTT showed water content dependence and low ΔC p values, which difficulted the assignment of a glass transition. MTT appeared as an enthalpic relaxation independent on frequency or on water content. This transition was related to changes in mechanical properties and with the stabilization of proton mobility.",

keywords = "Biopolymer, Differential scanning calorimetry, Dynamic mechanical analysis, Enthalpic relaxation, Galactomannan (PubChem CID: 439336), Guar gum, Guar gum (PubChem CID: 44134661), Low field 1H NMR, Biopolymer, Differential scanning calorimetry, Dynamic mechanical analysis, Enthalpic relaxation, Galactomannan (PubChem CID: 439336), Guar gum, Guar gum (PubChem CID: 44134661), Low field 1H NMR",

author = "Busch, {Ver{\'o}nica M.} and Santagapita, {Patricio R.} and Paulo D{\'i}az-Calder{\'o}n and Enrione, {Javier I.} and Buera, {M. Pilar}",

year = "2019",

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doi = "10.1016/j.carbpol.2019.01.092",

language = "American English",

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AU - Busch, Verónica M.

AU - Santagapita, Patricio R.

AU - Díaz-Calderón, Paulo

AU - Enrione, Javier I.

AU - Buera, M. Pilar

PY - 2019/5/1

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AB - In the present work two galactomannans, vinal gum and guar gum, were evaluated by DSC, DMA and LF- 1 H NMR in order to compare them, establishing their potential operational application range and promoting the use of the non-conventional VG in foods or other products. Three endothermal transitions appeared when heating the samples in the DSC: one at temperatures −90 to −10 °C (LTT), other around 50 °C (MTT) and a third one between 50 and 100 °C (HTT). Both LTT and HTT showed water content dependence and low ΔC p values, which difficulted the assignment of a glass transition. MTT appeared as an enthalpic relaxation independent on frequency or on water content. This transition was related to changes in mechanical properties and with the stabilization of proton mobility.

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KW - Differential scanning calorimetry

KW - Dynamic mechanical analysis

KW - Enthalpic relaxation

KW - Galactomannan (PubChem CID: 439336)

KW - Guar gum

KW - Guar gum (PubChem CID: 44134661)

KW - Low field 1H NMR

KW - Biopolymer

KW - Differential scanning calorimetry

KW - Dynamic mechanical analysis

KW - Enthalpic relaxation

KW - Galactomannan (PubChem CID: 439336)

KW - Guar gum

KW - Guar gum (PubChem CID: 44134661)

KW - Low field 1H NMR

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